Unfortunately, your CD-ROM won't write to CD's - so you'll have to get a new one that can write. Decent CD/DVD writers cost about $40 online and are a snap to install.
First, remove the CD drive that's in there now. It'll be held in with clamps or screws. You may have to take the front off of the case to slide it out.
Once it's out, check the jumpers on the back to see what they're set at (CS or Cable Select is most common) - but since this is likely an older computer, you're likely to see it set as Master or Slave. You can tell this by the diagram that's located near the jumpers themselves. Here's a link on how to do it: http://www.pchardware.co.uk/install-optical-drive.php
Anyway, in older computers there was a standard - that is, the drive set as Master goes on the far end of the cable, while the drive set as Slave goes to the middle connector. Just figure out which one yours is and set the new one appropriately.
My browser caused a flood of traffic, sio my IP address was banned. Hope to fix it soon. Will get back to posting as soon as Im able. - John
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