Since water boils at 212 Fahrenheit that would be really hot. I would expect that if it were running anywhere near that hot it would have shut down.
Have you checked the MSI site for a utility to monitor temperatures? http://www.msi.com/service/download/
Evidently there are two or more version of this motherboard. You'll need to know which one possibly.
The NVIDIAฎ nTune is the easiest, fastest, and safest performance optimization and monitoring application available for your PC.
Improved dynamic overclocking / GPU overclocking
Benchmarking wizard / Saved system profiles
System troubleshooting / Improved system monitoring
Voltage and bus speed monitoring / Temperature and fan speed monitoring
Dynamically adjustable voltages and fan speeds / Dynamically adjustable memory timings
MSI Dual Core Center
Key components status hardware monitor
Monitor the CPU status
D.O.T. Technology up to 12% improvement
Optimize System status define
Adjustable & monitor with "Dual CoreCenter" on windows system
Auto speed up with system loading change
5 environment mode and 3 user define mode
Combine with VGA CoreCell 3D, totally called "Dual CoreCell"
If you are using an ATI graphic card, you must install ver. 8.41 driver and its additional applications to make Dual CoreCenter works normally. It is better to use recommended installation while installing an ATI VGA driver.