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If I leave my computer off overnight, or any significant amount of time, the internet won't work on the first boot. If i reboot after the initial boot then it works. So pretty much I have to start my computer up twice for the internet to work.
I would open the task manager after the first boot note what did load and is up and running, then do your second boot and compare. A digital camera would make the task easier, anyway there should be a clue to what may be missing then you can work on the problem. Right now it is just to vague!
True. I know that it most likely isn't anything in Services. I turned a bunch of internet related ones to automatic (someone suggested this), and that didn't help. Tomorrow when I go for the first boot I'll print screen my task manager before and after and post my results here.