The Windows Live Mail shouldn't be that much different from Windows Mail other than the fact that you have to install it first and have a Windows LIVE account.
To set up Windows Live Mail:
Tools --> accounts --> Add --> select email
enter your email address, password, display name and then check the box for manually configure server settings for email account
Next you will need to enter the mail settings for the account. You will need to get the incoming and outgoing mail servers and ports from your ISP or email provider.
And then you are all done!
Edited by azfreetech, 23 October 2009 - 05:42 PM.