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What program does it default to. There may be an option in that e-mail client that keeps setting it as the default. If you do not need it or use it then you could probably uninstall it and then set outlook express as the default again.
Let me know whats going on the more details we have, the better we can help.
Did removing the other email program work? If it didn't, did you look in IE, Properties, Programs Tab? I know that when I installed Office, mine changed to Outlook automatically. I had to go back into the IE Properties to change it.